Transportation

The automobile, in spite of reductions of emissions and improvements in fuel economy, remains the largest source of greenhouse gases.  And as developing countries such as China and India begin to purchase and use automobiles at a higher per-capita level, this problem will greatly increase. 

Ford, Honda, GM, BMW, Mazda, and others are developing hydrogen cars, powered either by fuel cells, or by internal combustion engines designed to run on hydrogen (such engines have to be tuned for the different combustion ratio and density of hydrogen, and also must be designed to resist the embrittlement of metal in the engine that exposure to hydrogen causes).  In fact, Honda has said they plan to sell or lease about 100 of their sleek fuel cell vehicles in 2008 in the U.S., and BMW will introduce their 2008 model 7 Series that is bimodal, in that it runs on hydrogen or gasoline.

The problems with hydrogen vehicles are (1) the difficulty of onboard hydrogen storage, (2) the cost of fuel cells, and other issues such as cold starting capability, (3) the lack of a hydrogen filling station infrastructure, and (4) the cost of hydrogen. 

Hydrogen as an onboard fuel would burn essentially clean, with only water vapor and a very small amount of NOx released (if internal combustion).  However, if the hydrogen is produced by steam methane reformation (SMR) which produces 10X or more, by weight, the carbon dioxide greenhouse gas for every unit of hydrogen produced, hydrogen cannot be claimed as a clean fuel.  And producing hydrogen from water with electrolysis produces even more carbon if the electricity is generated by coal or oil fired generators.  

Nanoptek’s Solar Hydrogen Generators plans to supply carbon-free locally-produced hydrogen to early adopters in hydrogen transportation. 


Ultra-distributed home refueling. 

There are at present only about 30 hydrogen stations in the U.S., most in California and Nevada, with one in Burlington Vermont, and one at Logan Airport in Boston.  Worldwide there are about 300.   So, the infrastructure is sparse.  And, most of these stations produce or receive hydrogen for which tremendous amounts of carbon have been released, so there is no net gain to the global environment.

It is easy to visualize 30 to 100 acres of Nanoptek Solar Hydrogen Generators supplying carbon-free hydrogen at a filling station along the superhighways in the Plains and in the Southwest.  But what about the neighborhood filling station? Although their need for the hydrogen would dictate a much smaller installation of a only few acres, that is still too large for most such stations.  Of course, larger Nanoptek installations could be placed regionally, and the hydrogen could be trucked into the filling station, similar to the trucked-in gasoline that they receive now. That can be an economically viable solution in many areas of the country, even with the added cost of compressing and trucking the hydrogen, because the range would be relatively small. 

Ultimately, however, we believe that an “ultra-distribution” is required, where many homeowners will be able to produce most of the hydrogen required for their vehicles right at home.  A rooftop area of about 50 ft by 50 ft would supply enough hydrogen for the driving needs of an average family of 4.  This is about the size of 2 in-ground pools, and with many newer homes is a typical rooftop area. 

Companies such as Honda and Nuvera are developing small hydrogen refueling appliances that apparently laypeople can use easily and safely.  But the source for the hydrogen is still natural gas and grid electricity.   Nanoptek plans to someday supply homeowners with their own “oil well”, supplying clean low-cost hydrogen to their vehicles.    

 
Green electric cars and Synfuel

There are two scenarios for clean carbon-free transportation that will likely evolve alongside of hydrogen transportation, and Nanoptek will be well positioned to be a strong player in both.

There are two well-developed infrastructures that can be used now for transportation.  The first is, of course, the electrical grid.  While it certainly needs updating and improvements, it works now.  We know how to push electrons around the country.  The second is the liquid fuel infrastructure.  Again, we know how to move gallons of liquid fuel around the country, and we do both very well.

Nanoptek’s “green” electricity.
  Many companies are working on electric cars, which recharge by plugging into the grid.  The beauty of this is that we can all “fill up” at home, and in a manner that is safe and that we are all comfortable with.  Advancements in battery technology and hybrid cars are bringing the commercial electric vehicle closer and closer.  The Chevy Volt may be out in a couple years.  But, while the average consumer thinks that these electric vehicles are good for the environment, the electricity is for the most part produced with power plants that are coal or petroleum burning, so once again carbon dioxide is produced and released into our atmosphere in providing the electricity for these “clean” cars.

Nanoptek's Solar Hydrogen Generators will produce clean electricity for the grid.  Customers who purchase electric vehicles, in many parts of the country, can now purchase “green” electricity from their electricity supplier, for a premium.  Nanoptek plans to supply a significant amount of that “green” electricity, thereby playing an enabling role in the evolution of truly green electric car transportation.

Synfuel. 
It has been known for decades that hydrogen can be combined with CO and other heavy hydrocarbons to produce a liquid fuel, syngas, which can be burned in internal combustion engine cars that are very similar to what we drive now.  Consider how quickly and seamlessly our gasoline changed to include 10% ethanol over the past couple years.  The required changes were made to the injectors and other engines parts by automakers in Detroit and elsewhere with nary a complaint.  Similarly, the infrastructure is already in place for this liquid fuel.  And the basis for the fuel is CO and hydrogen, where the CO is from sequestered carbon dioxide from sources such as electrical generation from coal or oil.  

Of course, combustion of syngas will still release carbon into the atmosphere from our vehicles.  However, the production of syngas also captures carbon in the process of linking hydrogen, carbon monoxide, and other chemicals to form the fuel. But at present, the hydrogen used is largely produced by either SMR (natural gas) or partial oxidation (coal), and so the carbon produced in these processes makes the synfuel quite bad in terms of production of global warming gas.

With Nanoptek supplying the hydrogen to produce syngas, the carbon production associated with the hydrogen is eliminated.  In this scenario, the syngas becomes nearly carbon neutral, in that the carbon released upon combustion in our vehicles is offset by the carbon captured in production of the syngas.

       

[1] Hydrogen Highway was coined in California to describe their hydrogen transportation program.